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Sodium phenoxide when heated with CO$_2$, under pressure at 125$^\circ$C yields a product which on acetylation produces C.
The major product C would be:
168飞艇 bdbb71e58e85279199f3545a7867da75
(a)
168飞艇 e5568e6f611c1f81a3ca6e9d13d12195

(b)
168飞艇 f37309104e6207c9adc5d66f13bfe44a

(c)
168飞艇 75ce556aaec2d0ae0191fdb07432ee2e

(d)
168飞艇 0a045aa5d1a269996ee33995c837f6b5

Answer
VerifiedVerified
302.7k+ views
Hint: This question is based on the concept of acetylation reaction. As we can see in the question that B to C conversion takes place through the acetyl group. This is the Kolbe-Schmitt reaction, so now the product can be identified.

Complete step by step answer:
Now, we will move step by step for this reaction.
As we know, sodium phenoxide is the sodium salt of phenol.
The first step is when sodium phenoxide reacts with carbon-dioxide at high temp, and 5 atm to produce the salicylate i.e.
168飞艇 4b1f20984497a62e79692dd99362d451


In the first step, we can see that phenol group is attached to the benzene ring, and COO- group is attached with the sodium ion.
Thus, the product formed in the first step is B.
Now, if we perform the further reaction to attain the product C, then there is a reaction of salicylate formed with the acid i.e. sulphuric acid in the presence of an acetyl group.
Thus, the product formed is
168飞艇 5dcdc221bc10b3c063e0ef006df64bd4


Here, we can see that –COOH group is attached at the ortho position, and the product formed is C i.e. salicylic acid.It is also known as aspirin.
The second step of this reaction is an example of acetylation reaction.
As mentioned the whole reaction i.e. from sodium phenoxide to the formation of salicylic acid is Kolbe-Schmitt reaction.
Hence, the major product formed C is
168飞艇 edf524978d6a05fb952ebb8e5fe1a668

The correct option is (C).

Note: Don’t get confused while writing the complete chemical reaction, just perform it step by step as shown. There is a difference between salicylate, and salicylic acid. Salicylic acid is formed by the reaction of salicylate with sulphuric acid. So, salicylate acts as a starting material for acetylation reaction.