According to MOT, which statement is correct about the Boron molecule?
A. It is diamagnetic in nature
B. It is paramagnetic in nature having magnetic moment $2.8BM$ by using spin only formula
C. It is paramagnetic but having magnetic moment $1.7BM$
D. Its bond order is $2$.
Answer
646.5k+ views
Hint: The attractive type of a substance can be dictated by inspecting its electron setup: in the event that it shows unpaired electrons, at that point the substance is paramagnetic; if all electrons are combined, the substance is diamagnetic.
Complete step by step answer:
Paramagnetism alludes to the attractive condition of a particle with at least one unpaired electron. The unpaired electrons are pulled in by an attractive field because of the electrons' attractive dipole minutes. Hund's Rule expresses that electrons must involve each orbital independently before any orbital is doubly involved. This may leave the molecule with numerous unpaired electrons.
Diamagnetic substances are described by matched electrons—aside from in the already talked about instance of progress metals, there are no unpaired electrons. As per the Pauli Exclusion Principle which expresses that no two indistinguishable electrons may take up a similar quantum state simultaneously, the electron turns are situated in inverse ways. This makes the attractive fields of the electrons offset; consequently there is no net attractive second, and the particle can't be pulled in into an attractive field.
The Boron particle has $2{s^2}2{p^1}$ as the electron arrangement. Which means only the $p$ electron is unpaired. Since it has one unpaired electron, it is paramagnetic.
Hence, number of unpaired electrons in boron = $n = 1$
Now spin only magnetic moment of boron = $\mu = \sqrt {n(n + 2)} $
Spin only magnetic moment of boron = $\mu = \sqrt {1(1 + 2)} $
Spin only magnetic moment of boron = $\mu = \sqrt 3 $
Spin only magnetic moment of boron = $\mu = 1.7BM$
Therefore option (C) is the correct answer.
Note:
In the ground state, just one. Yet, for holding, every one of the three valence electrons are utilized, and the molecule procures a somewhat energized state.
Complete step by step answer:
Paramagnetism alludes to the attractive condition of a particle with at least one unpaired electron. The unpaired electrons are pulled in by an attractive field because of the electrons' attractive dipole minutes. Hund's Rule expresses that electrons must involve each orbital independently before any orbital is doubly involved. This may leave the molecule with numerous unpaired electrons.
Diamagnetic substances are described by matched electrons—aside from in the already talked about instance of progress metals, there are no unpaired electrons. As per the Pauli Exclusion Principle which expresses that no two indistinguishable electrons may take up a similar quantum state simultaneously, the electron turns are situated in inverse ways. This makes the attractive fields of the electrons offset; consequently there is no net attractive second, and the particle can't be pulled in into an attractive field.
The Boron particle has $2{s^2}2{p^1}$ as the electron arrangement. Which means only the $p$ electron is unpaired. Since it has one unpaired electron, it is paramagnetic.
Hence, number of unpaired electrons in boron = $n = 1$
Now spin only magnetic moment of boron = $\mu = \sqrt {n(n + 2)} $
Spin only magnetic moment of boron = $\mu = \sqrt {1(1 + 2)} $
Spin only magnetic moment of boron = $\mu = \sqrt 3 $
Spin only magnetic moment of boron = $\mu = 1.7BM$
Therefore option (C) is the correct answer.
Note:
In the ground state, just one. Yet, for holding, every one of the three valence electrons are utilized, and the molecule procures a somewhat energized state.
Recently Updated Pages
If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

A car covers the first half distance between two places class 11 physics CBSE

The resultant of two vectors overrightarrow P and overrightarrow class 11 physics CBSE

Find the value of cos 135 class 11 maths CBSE

A mass M is held in place by an applied force F and class 11 physics CBSE

A solution of glucose in water is labelled as 10 dfracwv class 11 chemistry CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Find the value of the expression given below sin 30circ class 11 maths CBSE

What do you mean by retardation What is its SI uni class 11 physics CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Difference between physical and chemical change class 11 chemistry CBSE

