Order of reactivity of halogens towards hydrogen is:
[A]${{F}_{2}}>C{{l}_{2}}>B{{r}_{2}}>{{I}_{2}}$
[B]${{I}_{2}}>B{{r}_{2}}>C{{l}_{2}}>{{F}_{2}}$
[C]$C{{l}_{2}}>B{{r}_{2}}>{{I}_{2}}>{{F}_{2}}$
[D]$B{{r}_{2}}>C{{l}_{2}}>{{F}_{2}}>{{I}_{2}}$
Answer
660.9k+ views
Hint: Reactivity of the halogens depends on their electronegativity. Higher the electronegativity, higher will be the tendency of the halogens to protonate, thus it will have a higher reactivity towards hydrogen than other halogens.
Complete step by step answer:
Fluorine, chlorine, bromine and iodine are known as the halogens. They belong to Group 17 which we also know by the name halogen group. These halogens exist as a diatomic molecule.
Halogens are highly electronegative and they have 7 electrons in their valence shells. Gaining one electron gives them the stable noble gas configuration thus, the react readily with the Group 1 and 2 elements.
As mentioned above, halogens react readily with Group 1 and 2 elements and as hydrogen sits in Group 1, they react with hydrogen too.
Halogens react directly with hydrogen forming acids like hydrochloric acid, hydrobromic acid, hydroiodic acid and hydrofluoric acid.
As we know, the atomic radius increases down the group and due to this, the nuclear attraction faced by the valence shell electrons of the atom decreases, also down the group electronegativity decreases as, a smaller negative ion will have higher tendency to attract a proton towards itself than a bigger atom. Therefore on moving down the group, reactivity decreases.
We know that fluorine lies on the top in Group 17 followed by chlorine, bromine and iodine. Therefore, fluorine is the most reactive and iodine is the least.
Therefore, the correct order of reactivity of halogens towards hydrogen will be ${{F}_{2}}>C{{l}_{2}}>B{{r}_{2}}>{{I}_{2}}$.
Hence, the correct answer is option A.
Note:
The hydrogen halides are formed through covalent bonding. The order of acidity of the acids thus formed is the opposite of the reactivity order. HI is the strongest acid among the halogens. Due to its larger size, the bond length between the H-I atoms increases and results in the decrease of bond strength. Hydroiodic acid will lose its proton readily, thus is a stronger acid than the other halogen acids.
Complete step by step answer:
Fluorine, chlorine, bromine and iodine are known as the halogens. They belong to Group 17 which we also know by the name halogen group. These halogens exist as a diatomic molecule.
Halogens are highly electronegative and they have 7 electrons in their valence shells. Gaining one electron gives them the stable noble gas configuration thus, the react readily with the Group 1 and 2 elements.
As mentioned above, halogens react readily with Group 1 and 2 elements and as hydrogen sits in Group 1, they react with hydrogen too.
Halogens react directly with hydrogen forming acids like hydrochloric acid, hydrobromic acid, hydroiodic acid and hydrofluoric acid.
As we know, the atomic radius increases down the group and due to this, the nuclear attraction faced by the valence shell electrons of the atom decreases, also down the group electronegativity decreases as, a smaller negative ion will have higher tendency to attract a proton towards itself than a bigger atom. Therefore on moving down the group, reactivity decreases.
We know that fluorine lies on the top in Group 17 followed by chlorine, bromine and iodine. Therefore, fluorine is the most reactive and iodine is the least.
Therefore, the correct order of reactivity of halogens towards hydrogen will be ${{F}_{2}}>C{{l}_{2}}>B{{r}_{2}}>{{I}_{2}}$.
Hence, the correct answer is option A.
Note:
The hydrogen halides are formed through covalent bonding. The order of acidity of the acids thus formed is the opposite of the reactivity order. HI is the strongest acid among the halogens. Due to its larger size, the bond length between the H-I atoms increases and results in the decrease of bond strength. Hydroiodic acid will lose its proton readily, thus is a stronger acid than the other halogen acids.
Recently Updated Pages
If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

A car covers the first half distance between two places class 11 physics CBSE

The resultant of two vectors overrightarrow P and overrightarrow class 11 physics CBSE

Find the value of cos 135 class 11 maths CBSE

A mass M is held in place by an applied force F and class 11 physics CBSE

A solution of glucose in water is labelled as 10 dfracwv class 11 chemistry CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Find the value of the expression given below sin 30circ class 11 maths CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Proton was discovered by A Thomson B Rutherford C Chadwick class 11 chemistry CBSE

Bond order ofO2 O2+ O2 and O22 is in order A O2 langle class 11 chemistry CBSE

