The correct decreasing order of basic strength of the following species is:
$ {H_2}O,N{H_3},O{H^ - },N{H_2}^ - $
(A) $ N{H_2}^ - > O{H^ - } > N{H_3} > {H_2}O $
(B) $ O{H^ - } > N{H_2}^ - > {H_2}O > N{H_3} $
(C) $ N{H_3} > {H_2}O > N{H_2}^ - > O{H^ - } $
(D) $ {H_2}O > N{H_3} > O{H^ - } > N{H_2}^ - $
Answer
563.4k+ views
Hint: The basic strength means the capability of donating electrons or the capability of abstraction of a proton. The presence of lone pairs of electrons in atoms makes the molecule to be more basic. Ammonia is more basic than water. Thus, the conjugate base of ammonia is more basic than the conjugate base of water.
Complete answer:
Water is a molecule that contains an oxygen atom and two hydrogen atoms. Oxygen has two lone pairs of electrons in water molecules, which makes the water basic, but actually water is a neutral compound.
Due to the presence of lone pairs of electrons on nitrogen in ammonia, ammonia can be considered as a base. But, due to the low electronegativity value of nitrogen compared to oxygen. Ammonia is more basic than water.
The conjugate base of ammonia is amine ion, it is more basic than ammonia. The conjugate base of water is hydroxide ion, it is more basic than water.
The group $ N{H_2}^ - $ is more basic in all the given molecules or groups.
Thus, the order of decreasing basic strength is $ N{H_2}^ - > O{H^ - } > N{H_3} > {H_2}O $
Option A is the correct one.
Note:
The compounds that will release a proton can be called an acid. The group that can have one less number of hydrogen atoms with a negative charge to its acid, can be considered as a conjugate base. Conjugate base of ammonia $ \left( {N{H_3}} \right) $ is $ N{H_2}^ - $ , similarly the conjugate base of water $ \left( {{H_2}O} \right) $ is $ O{H^ - } $ .
Complete answer:
Water is a molecule that contains an oxygen atom and two hydrogen atoms. Oxygen has two lone pairs of electrons in water molecules, which makes the water basic, but actually water is a neutral compound.
Due to the presence of lone pairs of electrons on nitrogen in ammonia, ammonia can be considered as a base. But, due to the low electronegativity value of nitrogen compared to oxygen. Ammonia is more basic than water.
The conjugate base of ammonia is amine ion, it is more basic than ammonia. The conjugate base of water is hydroxide ion, it is more basic than water.
The group $ N{H_2}^ - $ is more basic in all the given molecules or groups.
Thus, the order of decreasing basic strength is $ N{H_2}^ - > O{H^ - } > N{H_3} > {H_2}O $
Option A is the correct one.
Note:
The compounds that will release a proton can be called an acid. The group that can have one less number of hydrogen atoms with a negative charge to its acid, can be considered as a conjugate base. Conjugate base of ammonia $ \left( {N{H_3}} \right) $ is $ N{H_2}^ - $ , similarly the conjugate base of water $ \left( {{H_2}O} \right) $ is $ O{H^ - } $ .
Recently Updated Pages
Write structures of the following compounds i 2 Chloro3methylpentane class 11 chemistry CBSE

What is BLO What is the full form of BLO class 8 social science CBSE

Explain the Treaty of Vienna of 1815 class 10 social science CBSE

A Paragraph on Pollution in about 100-150 Words

XIX+XXX A 49 B 51 C 55 D 44 class 5 maths CBSE

If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Find the value of the expression given below sin 30circ class 11 maths CBSE

What do you mean by retardation What is its SI uni class 11 physics CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Difference between physical and chemical change class 11 chemistry CBSE

