Using the data given, find out in which option the order of reducing power is correct.
\[E_{C{r_2}O_7^{2 - }|C{r^{3 + }}}^\theta \] = 1.33 V
\[E_{C{r_2}|C{l^ - }}^\theta \] = 1.36 V
\[E_{MnO_4^ - |M{n^{2 + }}}^\theta \] = 1.51 V
\[E_{C{r^{3 + }}|Cr}^\theta \] = -0.74V
A. \[C{r^{3 + }}\] < \[C{l^ - }\] < \[M{n^{2 + }}\] < Cr
B. \[M{n^{2 + }}\] < \[C{l^ - }\] < \[C{r^{3 + }}\] < Cr
C. \[C{r^{3 + }}\] < \[C{l^ - }\] < \[C{r_2}O_7^{2 - }\] < \[MnO_4^ - \]
D. \[M{n^{2 + }}\] < \[C{r^{3 + }}\] < \[C{l^ - }\] < Cr
Answer
651k+ views
Hint: We can define the reducing character of an atom or a molecule to be the tendency of the given atom or molecule to reduce other chemical species. To put it in simpler terms, in order to reduce other chemical species, the given atom or molecule must itself undergo oxidation. This character is also known as the basic character of a given chemical species. Hence, the reducing character of a given substance is dependent on its basic character
Complete Step-by-Step Answer:
Before we move towards the solution of the given question, let us first understand some important basic concepts.
The electrode potential of hydrogen is considered to be zero as convention everywhere. This gives us a base from where we can find the relative increase or decrease in the reduction potential of the given species.
Electrochemical series is an arrangement of such species in accordance with their reduction potentials with respect to the reduction potential of hydrogen. Now, as we move down in the electrochemical series, the reduction potential decreases. The relation between reduction potential and reducing power is inverse in nature.
In the options given, we can observe the reduction potential in the order:
\[M{n^{2 + }}\] > \[C{l^ - }\] > \[C{r^{3 + }}\] > Cr
Hence, the reducing power of these species can be given in the order:
\[M{n^{2 + }}\] < \[C{l^ - }\] < \[C{r^{3 + }}\] < Cr
Hence, Option B is the correct option
Note: Reduction potential can be understood as the measure of the tendency for a given chemical species to accept electrons from other chemical substituents. It is basically the tendency of a species to get reduced by accepting an electron and is quantified on the basis of the electrochemical reference of hydrogen.
Complete Step-by-Step Answer:
Before we move towards the solution of the given question, let us first understand some important basic concepts.
The electrode potential of hydrogen is considered to be zero as convention everywhere. This gives us a base from where we can find the relative increase or decrease in the reduction potential of the given species.
Electrochemical series is an arrangement of such species in accordance with their reduction potentials with respect to the reduction potential of hydrogen. Now, as we move down in the electrochemical series, the reduction potential decreases. The relation between reduction potential and reducing power is inverse in nature.
In the options given, we can observe the reduction potential in the order:
\[M{n^{2 + }}\] > \[C{l^ - }\] > \[C{r^{3 + }}\] > Cr
Hence, the reducing power of these species can be given in the order:
\[M{n^{2 + }}\] < \[C{l^ - }\] < \[C{r^{3 + }}\] < Cr
Hence, Option B is the correct option
Note: Reduction potential can be understood as the measure of the tendency for a given chemical species to accept electrons from other chemical substituents. It is basically the tendency of a species to get reduced by accepting an electron and is quantified on the basis of the electrochemical reference of hydrogen.
Recently Updated Pages
Write structures of the following compounds i 2 Chloro3methylpentane class 11 chemistry CBSE

What is BLO What is the full form of BLO class 8 social science CBSE

Explain the Treaty of Vienna of 1815 class 10 social science CBSE

A Paragraph on Pollution in about 100-150 Words

XIX+XXX A 49 B 51 C 55 D 44 class 5 maths CBSE

If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

What do you mean by retardation What is its SI uni class 11 physics CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Difference between physical and chemical change class 11 chemistry CBSE

Proton was discovered by A Thomson B Rutherford C Chadwick class 11 chemistry CBSE

